基于BIM技术和有限元的检测与分析在PC结构中的应用研究

本文建立了PC结构施工全过程的BIM模型及有限元分析模型,对施工过程进行数值模拟与动态、静态监测,对装配式结构进行了结构性能评价,为结构可视化施工监测提供了技术支持。     

CuInS2/SiNWs/Si composite material for application as potential photoelectrode for photoelectrochemical hydrogen generation

This work aims at developing a new composite material based on nanosized semiconducting CuInS₂ (CIS) particles combined with silicon nanowires grown on a silicon substrate (SiNWs/Si) for photoelectrochemical (PEC)-splitting of water. The CIS particles were prepared via a colloidal method using N-methylimidazole (NMI) as the solvent and an annealing treatment. The SiNWs were obtained by chemical etching of silicon (100) substrates assisted by a metal. The CIS/SiNWs/Si composite material was obtained by deposition of an aliquot of a suspension of CIS particles onto the SiNWs/Si substrate, using spin coating followed by a drying step. The XRD pattern demonstrated that CuInS₂ grows in the tetragonal/chalcopyrite phase, while SiNWs/Si presents a cubic structure. The SEM images show semi-spherical particles (～10 nm) distributed on the surface of silicon nanowires (～10 μm). The EIS measurements reveal n-type conductivity for CIS, SiNWs/Si and CIS/SiNWs/Si materials, which could favour the oxidation reaction of water molecules.     

Preparation of YSZ porous ceramics with precise porosity control

Conventional preparation of porous ceramics often hard to accurately control the porosity of the samples. In this paper, by improving the foaming method, the foaming process is placed in the limited space of the ball mill tank, and YSZ porous ceramics with different porosity are obtained by changing the amount of slurry. Initial results showed that the porosity of the sample varies linearly with the increasing of addition of slurry. From the microscopic morphology, it can be seen that the increase in slurry content will reduce the number of pore with little changed size, which lead to the decrease in porosity. Therefore, with simple calculation YSZ porous ceramics with 85%, 80%, 75%, 70%, and 65% porosity can be obtained using the method of foaming in limited space by ball milling.     

纳米纤维素的疏水改性及应用研究进展

纳米纤维素作为一种性能优越的可再生纳米材料，应用前景极为广阔。然而，由于纳米纤维素结构上富含羟基，使其具有极强的亲水性，严重影响了纳米纤维素的疏水性能，并且在一定程度上限制了其在复合材料领域的应用。综述了纳米纤维素疏水改性的研究进展，从物理吸附、表面化学修饰（甲硅烷化、烷酰化、酯化等）、聚合物接枝共聚3个方面简述了目前应用较为广泛的疏水化改性方法，并对疏水纳米纤维素在包装材料、造纸、水净化等方面的应用现状进行了总结。最后对疏水改性纳米纤维素的未来发展进行了展望，旨在为疏水纳米纤维素的研究和应用提供参考。     

太赫兹可调谐滤波器设计

为了实现太赫兹信号的可调谐滤波，设计了一种基于柔性材料的太赫兹可调谐滤波器。通过扭曲特氟龙（Teflon）波导形成环型谐振器，实现了160～200 GHz频段的带阻滤波功能。改变谐振腔长可实现自由频谱范围（FSR）和滤波频点的调谐，实验测试了自由频谱范围在1.9 GHz和2.8 GHz间切换以及相应的滤波特性。研究表明，谐振腔长一定时，改变弯曲半径可实现滤波阻带抑制度的调节，柔性材料太赫兹环型谐振器可用于可调谐滤波，且具有较高的自由度。     

Temperature- and pH-sensitive core–shell nanogels as efficient carriers of doxorubicin with potential application in lung cancer treatment

Temperature- and pH-sensitive core–shell nanogels were prepared by one-pot soapless emulsion polymerization of N-isopropylacrylamide and 2-methacryloyloxy benzoic acid with the aid of a crosslinker (core) using poly(ethylene glycol) methyl ether methacrylate as stabilizer (shell). The size of nanogels depended on the crosslinker used, being considerable smaller (around 100?nm) with the use of the acid-labile crosslinker 9-divinyl-2,4,8,10-tetraoxaspiro[5.5]-undecane (DVA). Doxorubicine (DOX) was loaded in nanogels with good efficiency. The empty nanogels were biocompatible for a lung cancer cell line (NCI-H1437), while the DOX-loaded, DVA-crosslinked nanogels resulted with efficient cytotoxicity for that cell line.     

Developing microencapsulated 12‐hydroxystearic acid (HSA) for phase change material use

Phase change materials (PCM) have an increasingly more important role as a thermal energy storage (TES) media. However, leakage problem of PCM causes limitation during their integration in TES systems. Therefore, the encapsulation of PCMs is attracting research interest to extend usage of PCMs in real TES applications in recent years. In this study, hydroxystearic acid (HSA) was encapsulated with polymethyl methacrylate (PMMA) and different PMMA comonomer shells via emulsion polymerization method for the first time in literature. HSA with high melting temperature range (74–78°C) can widen the scope of using PCMs, and the encapsulated form can make it more versatile. The chemical structures, morphologies, and thermophysical properties of capsules were determined by FT‐IR, SEM, DSC, TGA, and thermal infrared camera. Among the produced HSA capsule candidates, PMMA‐HEMA is the most promising with latent heat of 48.5 J/g with melting range of 47 to 85°C. SEM analysis indicated that the capsules have spherical shape with compact surface at nano‐micro (100–440 nm) size range; however, some capsules exhibited agglomeration.     

Airborne bacterial assemblage in a zero carbon building: A case study

Currently, there is little information pertaining to the airborne bacterial communities of green buildings. In this case study, the air bacterial community of a zero carbon building (ZCB) in Hong Kong was characterized by targeting the bacterial 16S rRNA gene. Bacteria associated with the outdoor environment dominated the indoor airborne bacterial assemblage, with a modest contribution from bacteria associated with human skin. Differences in overall community diversity, membership, and composition associated with short (day‐to‐day) and long‐term temporal properties were detected, which may have been driven by specific environmental genera and taxa. Furthermore, time‐decay relationships in community membership (based on unweighted UniFrac distances) and composition (based on weighted UniFrac distances) differed depending on the season and sampling location. A Bayesian source‐tracking approach further supported the importance of adjacent outdoor air bacterial assemblage in sourcing the ZCB indoor bioaerosol. Despite the unique building attributes, the ZCB microbial assemblage detected and its temporal characteristics were not dissimilar to that of conventional built environments investigated previously. Future controlled experiments and microbial assemblage investigations of other ZCBs will undoubtedly uncover additional knowledge related to how airborne bacteria in green buildings may be influenced by their distinctive architectural attributes.     

Outcome‐based ventilation: A framework for assessing performance,health, and energy impacts to inform office building ventilation decisions

This article presents an outcome‐based ventilation (OBV) framework, which combines competing ventilation impacts into a monetized loss function ($/occ/h) used to inform ventilation rate decisions. The OBV framework, developed for U.S. offices, considers six outcomes of increasing ventilation: profitable outcomes realized from improvements in occupant work performance and sick leave absenteeism; health outcomes from occupant exposure to outdoor fine particles and ozone; and energy outcomes from electricity and natural gas usage. We used the literature to set low, medium, and high reference values for OBV loss function parameters, and evaluated the framework and outcome‐based ventilation rates using a simulated U.S. office stock dataset and a case study in New York City. With parameters for all outcomes set at medium values derived from literature‐based central estimates, higher ventilation rates’ profitable benefits dominated negative health and energy impacts, and the OBV framework suggested ventilation should be ≥45 L/s/occ, much higher than the baseline ~8.5 L/s/occ rate prescribed by ASHRAE 62.1. Only when combining very low parameter estimates for profitable impacts with very high ones for health and energy impacts were all outcomes on the same order. Even then, however, outcome‐based ventilation rates were often twice the baseline rate or more.     

高性能有机氟材料制备科学及应用进展

有机氟材料具有优异的热氧稳定性、耐化学腐蚀性、耐老化性、不黏性、电绝缘性以及极小的摩擦系数等特性，因此作为一种不可替代的材料广泛应用于高新技术产业。近年来高新技术产业发展对高性能有机氟材料的需求引发了学术界和工业界对氟材料的研究兴趣。依据本文作者的研究经历及有机氟材料的发展方向，本文介绍了氟树脂（新型含氟聚合物、电活性含氟聚合物、新型全氟磺酸聚合物、聚四氟乙烯3D打印）及氟橡胶（过氧化物硫化氟橡胶、耐低温氟醚橡胶、耐高温全氟醚橡胶、全氟聚醚基类玻璃橡胶）的制备科学及应用进展，特别阐述为了满足航空航天、能源、信息等高新技术产业需求发展的新一代高性能有机氟材料。本文也介绍了近期出现的聚四氟乙烯新成型技术及类玻璃氟橡胶。文章指出发展绿色环保和高效的高性能有机氟材料制备及成型加工方法是今后的发展方向。